Utilization of H₂SO₄ Activated PDAM Sludge as an Adsorbent with Alum Addition for Reducing COD and BOD in Batik Wastewater from Kutawaru, Cilacap
DOI:
https://doi.org/10.32493/jitk.v10i2.58425Keywords:
PDAM sludge, acid activation, batik wastewater, adsorption, alum dosageAbstract
This research aims to utilize PDAM Cilacap sludge waste as an adsorbent to treat wastewater from the batik industry from Kutawaru, which has levels of Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) that exceed quality standards. The sludge was chemically activated using 2 M H₂SO₄, then applied through laboratory-scale experiments with variations in alum doses (1, 2, and 3 g). The treatment results showed a significant decrease in the pollutant load. The initial BOD level of 1,800 mg/L decreased to 239-241 mg/L (86.6% efficiency), while the COD level decreased from 2,688 mg/L to 348-449 mg/L (83.3% efficiency). The adsorption and neutralization process also succeeded in raising the pH from 3.0 to 6.8-7.2 and effectively clarified the color of the waste. Although effluent has not fully met quality standards, activated PDAM sludge has proven to be promising as a low-cost and environmentally friendly adsorbent alternative to reduce organic pollutants from batik waste.
References
Astuti, W., & Handayani, D. (2020). Pemanfaatan lumpur PDAM sebagai bahan baku adsorben untuk pengolahan air limbah domestik. Jurnal Pengelolaan Sumber Daya Alam dan Lingkungan, 10(4), 560–569.
Anggriawan, A., Atwanda, M. Y., Lubis, N., & Fathoni, R. (2019). Kemampuan adsorpsi logam berat Cu menggunakan adsorben kulit jagung (Zea mays). Jurnal Chemurgy, 3(2), 27. https://doi.org/10.30872/cmg.v3i2.3581.
Apriyani, N. (2018). Industri batik: Kandungan limbah cair dan metode pengolahannya. Media Ilmiah Teknik Lingkungan, 3(1), 21–29. https://doi.org/10.33084/mitl.v3i1.640.
Desti, I., & Ula, A. (2021). Analisis sumber daya alam air. Jurnal Sains Edukatika Indonesia (JSEI), 3(2), 17–24.
Faizah, M., Rizky, A., Zamroni, A., & Khasan, U. (2022). Pembuatan briket sebagai upaya pemanfaatan limbah pertanian bonggol jagung di Desa Tampingmojo. Jumat Pertanian: Jurnal Pengabdian Masyarakat, 3(2), 65–68. https://doi.org/10.32764/abdimasper.v3i2.2863.
Fidiastuti, H., & Lathifah, A. (2018). Uji karakteristik limbah cair industri batik Tulungagung: Penelitian pendahuluan. Seminar Nasional Pendidikan Biologi dan Saintek III, 296–300.
Fitriani, L., & Nugroho, S. (2019). Studi efisiensi adsorpsi limbah cair batik menggunakan zeolit alam dan lumpur aktif. Jurnal Sains dan Teknologi Lingkungan, 11(3), 155–163.
Harahap, M. R., Amanda, L. D., & Matondang, A. H. (2022). Analisis kadar COD (chemical oxygen demand) dan TSS (total suspended solid) pada limbah cair menggunakan spektrofotometer UV-Vis. Amina, 2(2), 79–83. https://doi.org/10.22373/amina.v2i2.772.
Harmawan, T. (2022). Analisis kandungan minyak dan lemak pada limbah outlet pabrik kelapa sawit. QUIMICA: Jurnal Kimia Sains dan Terapan, 4(1), 15–19. https://doi.org/10.33059/jq.v4i1.4318.
Jariah, E., & Cahyadi, F. (2023). Efektivitas aktivasi asam dan basa pada lumpur PDAM dalam penurunan parameter organik limbah cair. Indonesian Journal of Environmental Science, 12(1), 35–47.
Kasman, M., Riyanti, A., & Kartikawati, C. E. (2019). Fitoremediasi logam aluminium pada lumpur instalasi pengolahan air menggunakan tanaman melati air (Echinodorus palaefolius). Jurnal Daur Lingkungan, 2(1), 7. https://doi.org/10.33087/daurling.v2i1.17
KLHK. (2019). Peraturan Menteri Lingkungan Hidup dan Kehutanan Republik Indonesia Nomor P.16 Tahun 2019 tentang baku mutu air limbah.
Khuzaimah, S. (2024). Manfaat aktivasi fly ash batu bara dengan variasi konsentrasi NaOH sebagai adsorben. Jurnal Inovasi Daerah, 3(1), 52–60. https://doi.org/10.56655/jid.v3i1.146.
Martini, S., Yuliwati, E., & Kharismadewi, D. (2020). Pembuatan teknologi pengolahan limbah cair industri. Jurnal Distilasi, 5(2), 26. https://doi.org/10.32502/jd.v5i2.3030.
Nuraini, R. (2021). Karakterisasi komposisi kimia lumpur PDAM dan potensinya sebagai adsorben limbah industri. Jurnal Teknologi Material dan Lingkungan, 7(1), 42–50.
Purba, B. S. A. (2020). Kinetika adsorpsi logam Zn menggunakan karbon aktif magnetik berbasis limbah biomassa.
Rahmawati, D., & Prasetyo, D. (2021). Pemanfaatan lumpur PDAM sebagai adsorben untuk pengolahan limbah cair industri batik. Jurnal Rekayasa Lingkungan, 15(2), 65–72.
Ramadhani, A., & Khuzaimah, S. (2023). Pemanfaatan limbah FABA (fly ash bottom ash) PLTU Karangkandri sebagai adsorben pengolahan limbah batik di Desa Kutawaru Cilacap. Jurnal Rekayasa Bahan Alam dan Energi Berkelanjutan, 7(2), 25–32. https://doi.org/10.21776/ub.rbaet.2023.007.02.04.
Sari, N. P., & Kusuma, R. (2022). Optimasi proses adsorpsi limbah cair batik menggunakan material berbasis silika-alumina. Jurnal Kimia Terapan Indonesia, 24(1), 21–28.
Suryani, T., & Maulana, H. (2018). Studi pemanfaatan lumpur PDAM sebagai material alternatif pengolahan limbah. Jurnal Teknologi dan Keberlanjutan, 6(2), 45–53.
Wahyudi, A. (2020). Aktivasi kimia lumpur PDAM menggunakan asam sulfat untuk peningkatan daya serap adsorben. Jurnal Teknologi Kimia, 9(1), 45–53.
Yuliana, F., & Putra, A. (2023). Analisis penurunan BOD dan COD limbah cair industri tekstil menggunakan adsorben alami teraktivasi. Jurnal Rekayasa Proses dan Lingkungan, 8(2), 87–96.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2026 Siti Khuzaimah

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.
Authors who publish with this journal agree to the following terms:
1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under creativecommons.org/licenses/by-sa/4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
Jurnal Ilmiah Teknik Kimia have CC-BY-SA or an equivalent license as the optimal license for the publication, distribution, use, and reuse of scholarly work.
In developing strategy and setting priorities, Jurnal Ilmiah Teknik Kimia recognize that free access is better than priced access, libre access is better than free access, and libre under CC-BY-SA or the equivalent is better than libre under more restrictive open licenses. We should achieve what we can when we can. We should not delay achieving free in order to achieve libre, and we should not stop with free when we can achieve libre.
Jurnal Ilmiah Teknik Kimia is licensed under a Creative Commons Attribution 4.0 International License
YOU ARE FREE TO:
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material for any purpose, even commercially.
- The licensor cannot revoke these freedoms as long as you follow the license terms.





