The Effectiveness of Coagulation-Flocculation and Filtration-Adsorption Combination Using Anionic Surfactant for COD Removal on Contaminated Well Water

Authors

  • Anisa Nabillah Universitas Sriwijaya
  • Nina Haryani Universitas Sriwijaya
  • Tine Aprianti Universitas Sriwijaya

DOI:

https://doi.org/10.32493/jitk.v10i2.61040

Keywords:

Anionic surfactants, Coagulation, Flocculation, Filtration, Adsorption

Abstract

Well water contaminated with hydrocarbons is generally characterized by high COD levels and acidic pH conditions, making it fail to meet clean water quality standards. This study aims to evaluate the effectiveness of a combination of anionic surfactants Linear Alkylbenzene Sulfonate, the role of ferric chloride and lime as coagulants in the coagulation and flocculation processes, and the filtration-adsorption process in improving water quality. Experiments were conducted with varying LAS concentrations (200–1000 ppm) through the stages of pretreatment, coagulation-flocculation, and filtration using silica sand, manganese, and activated carbon media. The results showed that the addition of LAS surfactant helped raise the pH toward neutral conditions. The optimum pH was achieved at a surfactant concentration of 400 ppm, with a pH of 7. The combination of coagulation-flocculation and filtration-adsorption processes was able to significantly reduce COD. The highest COD reduction efficiency was achieved in Treatment Variation 2 with filtration-adsorption at 85.3% at a concentration of 400 ppm, thereby meeting water quality standards (<10 mg/L). However, an excessive increase in LAS concentration reduced treatment efficiency due to adsorbent saturation and micelle formation. Overall, this combined method proved to be effective and practical for treating hydrocarbon-contaminated well water.

References

Abdillah, N. I., & Mirwan, M. (2024). Kombinasi Koagulasi – Flokulasi dan Filtrasi Menggunakan Bahan Alami Pada Limbah Cair Laundry Untuk Menurunkan Parameter TSS dan Kekeruhan. Serambi Engineering, IX(4), 11063–11077. https://repository.upnjatim.ac.id/id/eprint/31927

Aini, S., Dwi, H., & Priyono, K. (2021). Optimasi Dosis Koagulan Untuk Pengolahan Air Sungai Suko Optimization of Coagulant Dosage for Suko River Water Treatment. EKSERGI, 18(1), 1–6. https://doi.org/10.31315/e.v0i0.4497

Fadila, D. F. M., Mustain, A., & Dandel, B. F. (2024). Pengaruh Kecepatan Pengadukan Terhadap Penyisihan Parameter Nilai TSS dan Turbidity pada Proses Pengolahan Limbah Cair Industri Krimer. DISTILAT: Jurnal Teknologi Separasi, 10(9), 734–742. https://doi.org/https://doi.org/10.33795/distilat.v10i4.6607

Fadlilah, I., Pramita, A., Ayu, N., & Anggorowati, H. (2023). Pemanfaatan Karbon Aktif Kulit Pisang Kepok dan Karbon Aktif Tempurung Nipah sebagai Biosorben untuk Pengolahan Limbah Cair Laundry Utilization of Kepok Banana Peel Activated Carbon and Nipa Shell Activated Carbon as Biosorbents for Laundry Wastewater Tre. EKSERGI, 20(2), 118–123. https://doi.org/10.31315/e.v20i2.9681

Fasihah, N. S., Maryani, Y., & Heriyanto, H. (2022). Pengolahan Air Limbah Laundry Menggunakan Adsorbsi Cangkang Telur Ayam. Jurnal Ilmiah Wahana Pendidikan, 8(20), 129–139. https://doi.org/https://jurnal.peneliti.net/index.php/JIWP

Hari, B., Nurdini, L., Firdaus, M. C., & P, T. L. (2019). Metode Koagulasi dan Elektrokoagulasi dengan Penambahan Hidrogen Peroksida pada Proses Pengolahan Limbah Cair Buangan Laundry Coagulation and Electrocoagulation Methods with The Addition of Hydrogen Peroxide on Laundry Waste Treatment. EKSERGI, 16(2), 53–58. https://doi.org/10.31315/e.v16i2.2812

Hutabarat, D. M., Witasari, W. S., & Baskoro, R. (2022). Pengaruh Jenis Koagulan dan Variasi pH Terhadap Kualitas Limbah Cair di Instalasi Pengolahan Air Limbah PT Kawasan Industri Intiland. Teknologi Separasi, 8(9), 588–594. https:/doi.org/10.33795/distilat.v8i3.464

Kuyukina, M. S., Krivoruchko, A. V, & Ivshina, I. B. (2020). Advanced Bioreactor Treatments of Hydrocarbon-Containing Wastewater. 10(831). https://doi.org/10.3390/app10030831

Mawarni, E. D. A., Bieby Voijant Tangahu, & Ary Bachtiar Khrisna Putra. (2023). Aplikasi Surfaktan Alami dan Sintetis untuk Meningkatkan Penghilangan Total Petroleum Hidrokarbon dari Tanah Tercemar. Jurnal Serambi Engineering, 9(1), 7845–7852. https://doi.org/10.32672/jse.v9i1.776

Nugti, M. A., Mei, S., Cahyani, D., Latifah, L., & Sugiharto, A. (2020). Uji Efektifitas Koagulan Kapur (CaO), Ferri Klorida (FeCl3), Tawas (Al2(SO4)3) Terhadap Penurunan Kadar PO4 dan COD Pada Limbah Cair Domestik (Laundry) Dengan Metode Koagulasi. University Research Colloquium, 2, 345–348.

Rajabi, S., Ahmadian, F., Maleky, S., & Hashemi, H. (2025). Chemical coagulation / flocculation process in organic load reduction of machining oily effluent ( Z1 ): RSM ‑ CCD optimization. Applied Water Science, 15(252), 1–18. https://doi.org/https://doi.org/10.1007/s13201-025-02608-w

Rusdi, H. O., Wonorahardjo, S., Utomo, Y., & Wijaya, A. R. (2020). Pengaruh pH dan Konsentrasi Elektrolit dalam Elektrokoagulasi Limbah Surfaktan. JC-T(Journal Cis-Trans), 4(1), 21–28. https://doi.org/10.17977/um0260v4i12020p021

Santoso, B. A., & Apriani, I. (2024). Pengaruh Penambahan Koagulan Kapur ( CaO ) dan Ferri Klorida ( FeCl 3 ) terhadap Konsentrasi Logam Berat dan COD pada Air Limbah Laboratorium. Jurnal Teknologi Lingkungan Lahan Basah, 12(2), 385–394. https://doi.org/10.26418/jtllb.v12i2.76845

Septiani, M., Darajat, Z., Arham, M., Assumpta, M., Ole, N., & Fikri, Z. (2023). Kajian Isoterm Adsorpsi Linear Alkilbenzena Sulfonate ( LAS ) dalam Limbah Cair Detergen Menggunakan Biosorben Ampas Kopi dan Ampas Kelapa Study of Linear Alkylbenzena Sulfonate ( LAS ) Adsorption Isotherms in Detergent Wastewater Using Coffee Grounds and. EKSERGI, 20(2), 124–130. https://doi.org/10.31315/e.v20i2.9955

Wahyuni, A. R. T. (2019). Analisis Kemampuan Bakteri dari Perairan Tercemar yang Berpotensi Sebagai Agen Bioremediasi Limbah Hidrokarbon Minyak Solar (Tesis Prog). Univeritas Brawijaya. https://repository.ub.ac.id/id/eprint/177404

Windhono, F., Dzaky, M. M., Dewati, R., Windhono, F., Dzaky, M. M., & Dewati, R. (2023). Pemanfaatan Kitosan dari Cangkang Ranjungan Sebagai Biokoagulan pada Air Limbah Industri Tahu. Jurnal Teknik Kimia, 12(2), 56–60. https://doi.org/10.33005/jurnal_tekkim.v17i2.3782

Yusuf, Y., Fania, K., Chaerunnabila, S., Soeswanto, B., & Pasonang, R. (2024). Utilization of Coffee Grounds and Fly Ash as Adsorbents to Reduce Phosphate Content in Laundry Wastewater. 22(1), 33–38. https://doi.org/10.31315/s9s2n648

Zhao, X., Gong, L., Liao, G., Luan, H., Chen, Q., Liu, D., & Feng, Y. (2021). Micellar solubilization of petroleum fractions by heavy alkylbenzene sulfonate surfactant. Journal of Molecular Liquids, 329, 115519. https://doi.org/10.1016/j.molliq.2021.115519

Downloads

Published

2026-07-14

How to Cite

Nabillah, A., Haryani, N., & Aprianti, T. (2026). The Effectiveness of Coagulation-Flocculation and Filtration-Adsorption Combination Using Anionic Surfactant for COD Removal on Contaminated Well Water. Jurnal Ilmiah Teknik Kimia, 10(2), 152–160. https://doi.org/10.32493/jitk.v10i2.61040