ISOLASI DAN KARAKTERISASI SELULOSA : REVIEW

Authors

  • Irwan Mulyadi Universitas Pamulang

DOI:

https://doi.org/10.32493/jsmu.v1i2.2381

Keywords:

Selulosa, isolasi, hidrolisis asam, hidrolisis basa, ledakan uap, enzimatik, karakterisasi

Abstract

Selulosa, salah satu sumber daya alam terbaharukan yang melimpah di Indonesia. Keberadaan selulosa tidak terlepas dari lignoselulosa. Oleh karena it untuk mendapatkan selulosa harus dilakukan pengisolasian dari lignoselulosa tersebut. Penulisan ini bertujuan untuk mereview tentang isolasi dan karakterisasi selulosa tersebut. Isolasi selulosa dapat dilakukan dengan metode perlakuan hidolisis asam, hidrolisis basa, ledakan uap dan enzimatik. Karakterisasi isolasi dapt menggunakan 4 karakteristik yaitu analisis proxymate terutama kandingan selulosa dan lignin, analisis FTIR, analisis termal, dan analisis morfologi permukaan

 

Author Biography

Irwan Mulyadi, Universitas Pamulang

Dosen S1 Teknik Kimia Fakultas Teknik Unpam

References

Adel A M dan El-Shinnawy N A. 2012. Hypolipidemic applications of microcrystalline cellulose composite synthesized from different agricultural residues, Int. J. Biol. Macromol. 51(5) (2012) 1091-1102.

Azubuike C. 2012. Physicochemical, spectroscopic and thermal properties of powdered cellulose and microcrystalline cellulose derived from groundnut shells, J. Excipients Food Chem. 3(3) (2012) 106-115.

Bhattacharya D, Germinario LT, Winter WT. 2008. Isolation, preparation and characterization of cellulose microfibers obtained from bagasse. Carbohyd Polym. 73:371-377.

BPS. 2016. Statistik perkebunan Indonesia [Internet]. 2016 Desember: [diunduh 2019 februari 7]: Tangerang Selatan.

Castro C, Zuluaga R, Putaux JL, Caroa G, Mondragon I, Ganan P. 2011.Structural characterization of bacterial cellulose produced by gluconacetobacter swingsii sp from Colombian agroindustrial wastes. Carbohyd Polym. 84: 96–102

Chirayil CJ, Joy J, Mathew L, Mozetic M, Koetz, Thomsa S. 2014. Isolation and characterization of cellulose nanofibrils from helicteres isora plant. Indust Crops and Products. 59: 27-34.

Ekebafe LO, Ekebafe MO, Akpa FAO, Erhuanga G, Etiobhio BW. 2011. Graft copolymerization of acrylonitrile onto delignified native bamboo (Bambusa vulgaris) cellulosic and its utilization potential for heavy metal uptake from aqueous medium. CI & CEQ. 17(2):133-140.

Elanthikal S, Gopala KU, Varghese S, Guthrie JI. 2010. Cellulose microfibres produces from banana plant wastes: Isolation and Characterization. Carbohyd Polym. 80:852-859.

J. Goldstein, D.E. Newbury, P. Echlin, D.C. Joy, A.D. Romig Jr, C.E. Lyman, C. Fiori, E. Lifshin, Scanning electron microscopy and X-ray microanalysis: a text for biologists, materials scientists, and geologists, Springer Science & Business Media2012.

Hanna M, Biby G, Miladinov V. 2001. Production of microcrystalline cellulose by reactive extrusion, US Patent 6228213.

Jacquet N, Vanderghem , Danthine , Quievy N, Blecker C, Devaux J, Paquot M. 2012. Influence of steam explosion on physicochemical properties and hydrolysis rate of pure cellulose fibers, Bioresource Technol. 121 (2012) 221-227

Jufrinaldi. 2018. Isolasi selulosa dari bagas tebu melalui pemanasan iradiasi gelombang mikro. Jurn Ilmi Tek Kim UNPAM, Vol. 2 No. 2 : 36 – 46.

Karim M Z, Chowdhury Z Z, Hamid S B A, Ali M E. 2014. Statistical optimization for acid hydrolysis of microcrystalline cellulose and its physiochemical characterization by using metal ion catalyst, Materials 7(10) (2014) 6982-6999.

Klemm D, Philipp B, Heinze T, Heinze U, dan Wagenknecht W. 1998 Comprehensive Cellulose Chemistry:Fundamentals and Analytical Methods. Vol.1. Weiheim:Wiley-VCH Verlag GmBH.

Liu CF, Ren JL, Xu F, Liu JJ, Sun JX, Sun RC. 2006. Isolation and characterization of cellulose obtain from ultrasonic irradiated sugarcane bagasse. Jour of Agric Food Chem. 54(16):5742-8

Merci A, Urbano A, Grossmann M V A, Tischer C A, Mali S. 2015. Properties of microcrystalline cellulose extracted from soybean hulls by reactive extrusion, Food Res. Int. 73 (2015) 38-43

Milovanovic S, Markovic D, Aksentijevic K, Stojanovic DB, Ivanovic J, Zizovic I. 2016. Application of cellulose acetate for controlled release of thymol. Carbohyd Polym. doi:10.1016/j.carbpol.2016.03.093

Nuringtyas, Tri Rini. 2010. Karbohidrat. Gajah Mada University Press, Yogyakarta.

Poletto M, Junior HLO, Zattera AJ. 2014. Native cellulose: structure, characterization and thermal properties. mater. 7: 6105-6119. Doi:10.3390/ ma7096105

Pandey J, Takagi H, Nakagaito A, Kim H. 2015.Handbook of polymer nanocomposites. Processing, performance and application, Springer.

Princi E, Vicini S, Proietti N, Capitani D. 2005. Grafting polymerization on cellulose based textiles: a 13C solid state NMR characterization. European Polymer Journal. 41:1196-1203.

Purwaningsih H. 2012. Rekayasa biopolimer dari limbah pertanian berbasis selulusa dan aplikasinya sebagai material separator [Disertasi]. Bogor (ID):Institut Pertanian Bogor.

Rowell, Roger M. 2005. Chemical modification of wood. Handbook of wood chemistry and wood composites. Boca Raton, Fla. : CRC Press, 2005: pages 381-420.

Song Y. Zhou J, Zhang L, Wu X. 2008. Homogenous modification of cellulose with acrylamide in NaOH/urea aqueous solutions. Carbohydrate Polymers 73:18-25.

Sun JX, Sun XF, Zhao H, Sun RC. 2004. Isolation and characterization of cellulose from sugarcane bagasse. Jour Polymer Degrab Stab. 84:331-339.

Tibolla H, Pelissari FM, Menegalli FC. 2014. Cellulose nanofibers produced from banana peel by chemical and enzymatic treatment. LWT-Food Scien and Tech. 59:1311-1318.

Trache D, Donnot A, Khimeche K, Benelmir R, Brosse N. 2014. Physico-chemical properties and thermal stability of microcrystalline cellulose isolated from Alfa fibres, Carbohyd. Polym. 104 (2014) 223-230.

Xie J X, Yun C Y, De Hoop C F, Hu T, Qi J, Shupe T F. 2016. Isolation and characterization of cellulose nanofibers from bamboo using microwave liquefaction combined with chemical treatment and ultrasonication. Carbohyd Polym. doi:10.1016/j.carbpol.2016.06.011, forthcoming.

Zhang M, Qi W, Liu R, Su R, Wu S, He Z. 2010. Fractionating lignocellulose by formic acid: characterization of major components. Biomass and Bioen. 34: 525-532.

Zhou Y, Stuart-Williams H, Farquhar GD, Hocart CH. 2010. The use of natural abundance stable isotopic ratio to indicate the presence of oxygen-containing chemical linkages between cellulose and lignin in plant cell walls. Phytochemistry 71:982-993.

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Published

2019-02-27

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