The Effect of Chloride Ions for Corrosion Resistance of C276 Material in NaCl Solution
DOI:
https://doi.org/10.32493/pjte.v8i1.48481Keywords:
Hastealloy C276, Corrosion, chloride ion, electrochemical, Pitting PotentialAbstract
Hastealloy-C276 is an austenitic nickel-molybdenum-chromium alloy with small amounts of tungsten added. This material is quite familiar and is used in various industrial components. However, this alloy, like other types, is very susceptible to corrosion due to the influence of chloride ions in solution. The corrosion resistance of steel alloy materials was investigated using electrochemical methods including open circuit potential (OCP), Anodic Potentiodyamic (AP) with and Tafel in NaCl solution media. The test parameters carried out were chloride concentration (0.001 M-1M) and pH (2, 7 and 10) values. The test results show that an increase in chloride ion concentration causes a decrease in the OCP value in a negative direction, which indicates a tendency for decreasing of the corrosion resistance for C276. The AP test results show that the pitting potential (Epit) value slowly decreases as the chloride ion concentration increases up to 1 M. On the other hand, the role of pH is very important in changing the corrosion resistance performance. A decrease in pH to 2 causes an increase in the corrosion rate of the material, whereas an increase in pH causes this decrease.
References
[1] G. Priyotomo, “Deteksi Proses Korosi Pada Baja Dengan Menggunakan Lapisan Akrilik Termodifikasi Phenolphthalein,” J. Tek. Mesin Cakram, vol. 3, no. 2, pp. 55–62, Oct. 2020, doi: 10.32493/jtc.v3i2.7518.
[2] S. Harsimran, K. Santosh, and K. Rakesh, “Overview of Corrosion and Its Control: A Critical Review,” Proc. Eng. Sci., vol. 3, no. 1, pp. 13–24, 2021, doi: 10.24874/PES03.01.002.
[3] S.-H. Chen, “A Study of Correlation between Nickel-based Alloy Hastelloy-C276 Machining and Cutting Tool Life,” J. Chem. Pharm. Res., vol. 10, no. 12, pp. 35–50, 2018, [Online]. Available: https://www.jocpr.com/articles/a-study-of-correlation-between-nickelbased-alloy-hastelloyc276-machining-and-cutting-tool-life.pdf
[4] S. Y. Jiao, G. N. Zhu, J. X. Dong, and Q. Q. Zhang, “Carbide evolution and Mo depletion law in Hastelloy C-276,” Cailiao Gongcheng/Journal Mater. Eng., no. 1, 2011.
[5] G. Meng, Y. Li, Y. Shao, T. Zhang, Y. Wang, and F. Wang, “Effect of Cl- on the Properties of the Passive Films Formed on 316L Stainless Steel in Acidic Solution,” Journal of Materials Sciences and Technology, vol. 30, no. 3. pp. 253–258, 2013.
[6] H. Parangusan, J. Bhadra, and N. Al-Thani, “A review of passivity breakdown on metal surfaces: influence of chloride- and sulfide-ion concentrations, temperature, and pH,” Emergent Mater., vol. 4, no. 5, pp. 1187–1203, 2021, doi: 10.1007/s42247-021-00194-6.
[7] J. Soltis, “Passivity breakdown, pit initiation and propagation of pits in metallic materials – Review,” Corros. Sci., vol. 90, pp. 5–22, 2015, doi: https://doi.org/10.1016/j.corsci.2014.10.006.
[8] A. A. Dastgerdi, A. Brenna, M. Ormellese, M. Pedeferri, and F. Bolzoni, “Experimental design to study the influence of temperature, pH, and chloride concentration on the pitting and crevice corrosion of UNS S30403 stainless steel,” Corros. Sci., vol. 159, p. 108160, 2019, doi: https://doi.org/10.1016/j.corsci.2019.108160.
[9] Y. Chen, S. Shen, J. Gu, Z. Zhang, and N. Li, “Hot Chlorination Corrosion of Metallic Nickel by Chlorine Catalyzed by Sodium Chloride,” ACS Omega, vol. 5, no. 42, pp. 27278–27286, Oct. 2020, doi: 10.1021/acsomega.0c03486.
[10] W. Ding, A. Bonk, and T. Bauer, “Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated solar power plants: A review,” Front. Chem. Sci. Eng., vol. 12, no. 3, pp. 564–576, 2018, doi: 10.1007/s11705-018-1720-0.
[11] W. Ding et al., “Hot corrosion behavior of commercial alloys in thermal energy storage material of molten MgCl2/KCl/NaCl under inert atmosphere,” Sol. Energy Mater. Sol. Cells, vol. 184, pp. 22–30, 2018, doi: https://doi.org/10.1016/j.solmat.2018.04.025.
[12] X. Tang, S. Wang, D. Xu, Y. Gong, J. Zhang, and Y. Wang, “Corrosion Behavior of Ni-Based Alloys in Supercritical Water Containing High Concentrations of Salt and Oxygen,” Ind. Eng. Chem. Res., vol. 52, no. 51, pp. 18241–18250, Dec. 2013, doi: 10.1021/ie401258k.
[13] C. A. Loto, A. P. I. Popoola, O. S. Fayomi, and R. T. Loto, “Corrosion Polarization Behaviour of Type 316 Stainless Steel in Strong Acids and Acid Chlorides,” Int. J. Electrochem. Sci., vol. 7, no. 4, pp. 3787–3797, 2012, doi: https://doi.org/10.1016/S1452-3981(23)13997-6.
[14] J. R. da Cruz, M. S. F. de Lima, and R. Bertazzoli, “Corrosion Susceptibility and Functionally Graded Properties of Ti-35Nb-4Sn Alloy Processed by Laser Remelting,” Materials Research, vol. 23. scielo , 2020.
[15] G. Priyotomo, P. Sebleku, and Y. Kaneno, “Pitting Corrosion of Ni3(Si,Ti)+2Cr Intermetallic Compound at Various Chloride Concentrations,” Int. J. Sci. Eng., vol. 7, no. 1, pp. 10–15, Jul. 2014, doi: 10.12777/ijse.7.1.10-15.
[16] G. Priyotomo, P. Sebleku, and Y. Kaneno, “Pitting Corrosion of Ni3(Si,Ti)+4Al Intermetallic Compound at Various Chloride Concentrations,” Int. J. Sci. Eng., vol. 6, no. 2, pp. 81–85, 2014, doi: 10.12777/ijse.6.2.81-85.
[17] I. Bösing, “Modeling electrochemical oxide film growth—passive and transpassive behavior of iron electrodes in halide-free solution,” npj Mater. Degrad., vol. 7, no. 1, p. 53, 2023, doi: 10.1038/s41529-023-00369-y.
[18] A. Fattah-alhosseini, A. Saatchi, M. A. Golozar, and K. Raeissi, “The transpassive dissolution mechanism of 316L stainless steel,” Electrochim. Acta, vol. 54, no. 13, pp. 3645–3650, 2009, doi: https://doi.org/10.1016/j.electacta.2009.01.040.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2024 Gadang Priyotomo, Ahsonul Anam

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

