Penentuan Kadar Logam Berat (As, Ba, Cd, Cr, Hg, Pb, Sb, Se) pada Mainan Anak (Slime, Lapisan Cat, Cat Tangan) dengan Metode SNI ISO 8124-3:2010 Menggunakan ICP-OES
DOI:
https://doi.org/10.32493/jitk.v7i2.27676Keywords:
toys, heavy metals, slime, coating, finger paintAbstract
ABSTRACT
Safety of children's toys is an important factor that must be considered. Such as the heavy metal content of Arsenic, Barium, Cadmium, Chromium, Mercury, Lead, Antimony and Selenium. Heavy metals are carcinogenic and cause various diseases and poisonings. Heavy metal analysis was carried out using SNI ISO 8124-3 : 2010 method. Sample preparation was carried out by wet destruction which functions to decompose solids from analytes. Variations in the types of toy materials are also needed to see the difference in results. The ICP - OES instrument was chosen because it has a low detection limit, high selectivity, high precision and accuracy, and short measurement time. The instrument system uses plasma as the ionizer and Argon as the carrier gas. From the results of the analysis, the slime contained 0.4343 mg/kg Hg metal (yellow slime), 1.2974 mg/kg Sb metal and 0.5527 mg/kg Pb (red slime). The paint layer contains metal Ba 53.5587 mg/kg (dark green paint layer), metal Pb 1.3923 mg/kg (purple paint layer), metal Hg 0.4546 mg/kg and metal Sb 4.7480 mg/kg (pink paint layer). The hand paint contains As 0.7352 mg/kg (blue hand paint), Ba 61.1159 mg/kg (orange hand paint), 0.7417 mg/kg Hg metal (red hand paint) and 1.0344 Pb metal mg / kg ( purple hand paint ) . The three samples were still declared safe because all metals were still below the maximum limit based on SNI ISO 24-3: 2010.References
Badan Standardisasi Nasional. 2010. SNI ISO 8124-3. “Keamanan mainan - Bagian 3 : Migrasi unsur tertentuâ€. Badan Standardisasi Nasional: Jakarta.
Badan Standardisasi Nasional. 2014. “Sosialisasi SNI Mainan Anak: Persyaratan Dan Penerapanâ€. Pusat Pendidikan Dan Pemasyarakatan Standardisasi: Jakarta.
Gebel, T. (1997). Arsenic and antimony: comparative approach on mechanistic toxicology. Chemico-Biological Interactions, 107(3), 131–144. https://doi.org/https://doi.org/10.1016/S0009-2797(97)00087-2
Hamilton, S. J. (2004). Review of selenium toxicity in the aquatic food chain. Science of The Total Environment, 326(1), 1–31. https://doi.org/https://doi.org/10.1016/j.scitotenv.2004.01.019
Hazra, F., Purnama, S.P., Sari, S.M. (2014). Verifikasi Metode Uji Arsen dalam Contoh Mainan Anak. Jurnal Sains Terapan, 4(2). 36-45.
Hidayati, E. N., Alauhdin, M., & Prasetya, A. T. (2014). Perbandingan metode destruksi pada analisis Pb dalam rambut dengan AAS. Indonesian Journal of Chemical Science, 3(1).
Indirawati, S. (2017). Pencemaran Logam Berat Pb dan Cd dan keluhan kesehatan pada masyarakat di kawasan Pesisir Belawan. Jurnal Jumantik, 2(2), 54–60.
Indrawijaya, B., Oktavia, H., Cahyani, W. E., Studi, P., Kimia, T., Teknik, F., Pamulang, U., & Selatan, T. (2019). Penentuan Kadar Logam Berat (As, Ba, Cd, Cr, Hg, Pb, Sb, Se) Pada Mainan Anak Dengan Metode SNI ISO 8124-3:2010 Menggunakan ICP-OES Analysis. Jurnal Ilmiah Teknik Kimia, 3(2), 87–94.
Ishak, N. I. (2017). Analisis risiko lingkungan logam berat merkuri pada sedimen laut di wilayah pesisir kota Makassar. Promotif: Jurnal Kesehatan Masyarakat, 7(2), 88-92.
Kresse, R., Baudis, U., Jäger, P., Riechers, H. H., Wagner, H., Winkler, J., & Wolf, H. U. (2000). Barium and barium compounds. Ullmann's encyclopedia of industrial chemistry.
Rodiana, yayah, Masitoh, S., Maulana, H., & Nurhasni, N. (2013). Pengkajian Metode Untuk Analisis Total Logam Berat Dalam Sedimen Menggunakan Microwave Digestion. Jurnal Ecolab, 7(2), 71–80. https://doi.org/10.20886/jklh.2013.7.2.71-80
Sanusi, A.M., Rahayu, W.S., Utami, P.I. (2010). Identifikasi Cemaran Logam Timbal dalam Mainan Gigitan Bayi yang Beredar di Purwokerto dengan Metode Spektrofotometri Serapan Atom. Jurnal PHARMACY, 7(3), 123-134.
Sudarmaji Sudarmaji, J. Mukono, C. I. P. (2006). Toksikologi Logam Berat B3 Dan Dampaknya Terhadap Kesehatan. Jurnal Kesehatan Lingkungan, 2(23), 129–142.
Skoog, D.A, Holler, F.J., Crouch, S.R. (2018) Principles of Instrumental Analysis. Cengage Learning.
Syahfitri, W. Y. N., Muhayatun, M., Lestiani, D. D., & Adventini, N. (2009). Validasi Metode AAS Untuk Analisis Unsur Dalam Sampel Partikulat Udara
Downloads
Published
How to Cite
Issue
Section
License
Authors who publish with this journal agree to the following terms:
1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under creativecommons.org/licenses/by-sa/4.0 that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).
Jurnal Ilmiah Teknik Kimia have CC-BY-SA or an equivalent license as the optimal license for the publication, distribution, use, and reuse of scholarly work.
In developing strategy and setting priorities, Jurnal Ilmiah Teknik Kimia recognize that free access is better than priced access, libre access is better than free access, and libre under CC-BY-SA or the equivalent is better than libre under more restrictive open licenses. We should achieve what we can when we can. We should not delay achieving free in order to achieve libre, and we should not stop with free when we can achieve libre.
Jurnal Ilmiah Teknik Kimia is licensed under a Creative Commons Attribution 4.0 International License
YOU ARE FREE TO:
- Share — copy and redistribute the material in any medium or format
- Adapt — remix, transform, and build upon the material for any purpose, even commercially.
- The licensor cannot revoke these freedoms as long as you follow the license terms.