Penentuan Kandungan Phthalate Plastisizer DEHP (Bis (2-ethylhexyl) phthalate) pada Kemasan Makanan, Minuman dan Obat/Kosmetik Berbahan Plastik Dengan Metode EN71-5 Menggunakan GC-MS
DOI:
https://doi.org/10.32493/jitk.v7i2.27681Keywords:
plastic, packaging, phthalate, plasticizer, EN71-5Abstract
Food, beverage, medication, and cosmetic packaging are just a few examples of the numerous plastic items available today. Behind the shapes, colors, and size variations available on the market, the usage of plasticizers, which are additives that work to increase the resistance and flexibility of plastic materials, is one of the risks that hound consumers. The phthalates ester DEHP, which is a form of hazardous chemical called bis (2-ethylhexyl) phthalate, may be present in this plasticizer. Phthalates, according to research, can lower the level of the hormone testosterone, which in turn alters how the male reproductive system develops. From the research, phthalates have been linked to cancer also. Using the EN71-5 procedure, phthalate compounds in plastic products can be analyzed. The process of sample preparation involved extraction using a soxhlet extractor and the organic solvent n-Hexane. The samples were then subjected to GC-MS analysis. Because it offers high selectivity and accuracy in assessing complex chemical molecules, both quantitatively and qualitatively, the GC-MS (Gas Chromatography-Mass Spectrometer) is utilized. According to the analysis findings, the sample complies with Permendag No. 26 Tahun 2021's quality standards for goods containing hazardous chemicals because the amount of the phthalates DEHP (Bis (2-ethylhexyl) phthalate) compound was below the instrument's detection limit or it was not found in the sample. This sample test's findings only relate to the samples and/or products that were used in the test.
References
Ayamba, A. A., Ali, M., Carboo, D., & Awuku, F. J. (2018). Extraction and Determination of Phthalates Content in Polyethylene Food Contact Materials on the Ghanaian Market. Journal of Natural Sciences Research, 8(14), 1–6.
Badan Pusat Statistik, (2022). Ekonomi Indonesia Triwulan IV 2021 Tumbuh 5,02 Persen (yoy). Diakses pada 02/11/22, dari https://www.bps.go.id/ pressrelease/2022/02/07
EN71 Safety of toys - Part 5: Chemical toys (sets) other than experimental sets
EPMF. (2016). RISK MANAGEMENT OPTIONS ANALYSIS CHLORO PLATINATES - Final Report. 1–38.
Gray, L. E., Ostby, J., Furr, J., Price, M., Veeramachaneni, D. N. R., & Parks, L. (2000). Perinatal exposure to the phthalates DEHP, BBP, and DINP, but not DEP, DMP, or DOTP, alters sexual differentiation of the male rat. Toxicological Sciences, 58(2), 350–365. https://doi.org/10.1093/toxsci/58.2.350
Haskins, N. J. (1985). Gordon M. Massage. Practical aspects of gas chromatography mass spectrometry. John Wiley & Sons, 1984, ISBN 0â€471â€06277â€4. Price£ 69.35.
Indrawijaya, B., & Nugraha, W. (2021). Penentuan Kandungan Phthalate Plastisizer Dehp (Bis (2-Ethylhexyl) Phthalate) pada Botol Minuman Plastik dengan Metode EN71-5 Menggunakan GC-MS. Jurnal Ilmiah Teknik Kimia, 5(2), 87-91. doi:http://dx.doi.org/ 10.32493/jitk.v5i2.11298
Middleditch, B. S. (1979). Practical mass spectrometry. A contemporary introduction.
Ogonowski, M., schur,C., jersan, A. and Gorokhova, E. (2016). Physiological Effects of Plastic Wastes on the Endocrine System ( Bisphenol A , Physiological Effects of Plastic Wastes on the Endocrine System ( Bisphenol A , Phthalates , Bisphenol S , PBDEs , TBBPA ). … Journal of Bioinformatics and …, February 2020. https://www.research gate.net/profile/Chinaza-Awuchi/post/ What-is-your-opinion-about-plastic-waste/attachment/5e691518cfe4a7bbe5650307/AS%3A867942325551109%401583944984666/download/Physiological_Effects_of_Plastic_Wastes_on_the_End.pdf
Permendag no 26 tahun 2021, Metode Pengujian, Tata Cara Pendaftaran, Pengawasan, Penghentian Kegiatan Perdagangan Dan Penarikan Barang Terkait Dengan Keamanan, Keselamatan, Kesehatan, Dan Lingkungan Hidup. Kementerian Perdagangan Republik Indonesia. 2019
Rusyn, I., & Corton, J. C. (2012). Mechanistic considerations for human relevance of cancer hazard of di(2-ethylhexyl) phthalate. Mutation Research/Reviews in Mutation Research, 750(2), 141–158. https://doi.org/https://doi.org/10.1016/j.mrrev.2011.12.004
Shelby, M. D. (2006). NTP-CERHR monograph on the potential human reproductive and developmental effects of di (2-ethylhexyl) phthalate (DEHP). NTP CERHR MON, 18, v, vii–7, II-iii-xiii passim. http://europepmc.org/ abstract/ MED/19407857
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